The main thing to make sure of is that the connection between the ground side of the Duet VIN terminal block and the ground side of the VIN terminal block on that board is short and secure. If it is too long then noise on the ground wire could cause the stepper driver to malfunction. If the ground wire is not secure than that board could feed VIN into the step/dir/end signals or the +3.3V from the Duet and damage it.
This requirement is not specific to the Duet, it applies to connecting non-isolated expansion stepper drivers to any electronics.
The three red pins labelled V are probably all connected together on that board, in which case they should be connected to +3.3V from the expansion connector.
HTH David