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I am not a chemical expert but I can only guess that this same thing is happening with other filaments when they are spending too much time in the nozzle for a given temp.........................................
That's a definite, and can be one of the problems with a mixing hot end. What can happen is that the loaded but unused filaments "cook" inside the melt chamber even at normal printing temperatures if left for any length of time. Then when you come to start printing with that filament, what comes out to start with, for the first few mm, is a lot of vapour and a very runny, almost liquid messy stuff. You have to be aware of that and try to keep all the filaments moving, even slightly and/or arrange/slice the multi part object in such a way that no single filament is left unused in the melt chamber for too long.