DOH!!! Of course. I will give that a try.
Edit: That was it!! Of course, S1 is the default, so I actually had to set it to S0 when I got the "address" right. Final Result:
M584 X0 Y1 U2 Z3:4:5 ; X and Y for CoreXY. U for toolchanger lock. Z has three drivers for kinematic bed suspension.
M584 E1.0:1.1:22.0 ; Extruders for three tools. First two on 3HC 1, third one on Tool Board 22
M569 P0 S0 ; Drive 0 direction | X stepper
M569 P1 S0 ; Drive 1 direction | Y Stepper
M569 P2 S0 ; Drive 2 direction | U Tool Changer Lock
M569 P3 S0 ; Drive 3 direction | Front Left Z
M569 P4 S0 ; Drive 4 direction | Front Right Z
M569 P5 S0 ; Drive 5 direction | Back Z
; End of main board drivers. Expansion boards have three each.
; Expansion CAN 1
M569 P1.0 S1 ; Extruder T0
M569 P1.1 S1 ; Extruder T1
; At this moment, nothing on expansion CAN 2
; Tool board CAN 22
M569 P22.0 S0 ; Extruder T2
P.S. THANK YOU! I knew it was something I was staring right at and not seeing.