What is the specification of your motors, what power supply voltage are you using, and what are your steps/mm?
Have you gone through the calculation at https://duet3d.com/wiki/Choosing_stepper_motors#How_to_work_out_the_power_supply_voltage_you_need to see whether you can reach your desired speed without the back emf of the motor being larger than the power supply voltage? You will obviously need to calculate the revs per second allowing for your 10:1 gearboxes.
There is no maximum speed embedded in the firmware.