@droftarts @Phaedrux
I've finally found the cause of the issue.
When I installed my new router, around the same time my Iphone did an update.
So I had a look around on my Iphone, Settings, Security, Safari, and found that some settings weren't as they were or how I thought they should have been.
So I started tinkering around with some of these settings. Under Privacy and Security I found that "Prevent Cross-site Tracking", and "Block all Cookies", where both enabled.
With disabling these 2 settings, Wham bam thank you ma'am, Iphone is presenting the full ios DWC and it now appears in my routers client list.
How the heck was my iphone stopping the duet appearing on the router?
Surely having these 2 settings enabled on my iphone is just for the iphones security, not my router or network?
Anyway, it's now working and hope this may help others.
Thank you for your help.